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Standard Test Method for Water in Paints and Paint Materials by Karl Fischer Method 卡尔费休法测定涂料和涂料中水含量的标准试验方法
发布日期: 2022-12-01
1.1 本试验方法适用于所有油漆和油漆材料,包括树脂、单体和溶剂,醛和某些活性金属、金属氧化物和金属氢氧化物除外。虽然评估仅限于含水量在30 % 至70 % 范围内,有理由相信通过该测试方法可以确定较高和较低的浓度。 1.2 以国际单位制表示的数值应视为标准。括号中给出的值仅供参考。 1.3 本标准并不旨在解决与其使用相关的所有安全问题(如有)。本标准的使用者有责任在使用前建立适当的安全、健康和环境实践,并确定监管限制的适用性。 第节给出了具体的危害说明 7. . 1.4 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《国际标准、指南和建议制定原则决定》中确立的国际公认标准化原则制定的。 =====意义和用途====== 4.1 水含量的控制通常对控制涂料和涂料成分的性能非常重要,并且对控制挥发性有机化合物(VOC)含量至关重要。 4.2 涂料通常不溶于常见的卡尔费休溶剂,如甲醇。吡啶已被发现是这些材料的几乎通用溶剂;然而,在室温下在该溶剂中Karl Fischer反应太慢。为了加快速度,1-乙基哌啶在5 % 作为缓冲液或“催化剂”。 ” 4.3 对于非吡啶类试剂,可使用多种不同的溶剂体系来增加溶解度,并尽量减少酮和醛的干扰。
1.1 This test method is applicable to all paints and paint materials, including resins, monomers, and solvents, with the exception of aldehydes and certain active metals, metal oxides, and metal hydroxides. While the evaluation was limited to pigmented products containing amounts of water in the 30 % to 70 % range, there is reason to believe that higher and lower concentrations can be determined by this test method. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 7 . 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 4.1 Control of water content is often important in controlling the performance of paint and paint ingredients, and it is critical in controlling volatile organic compound (VOC) content. 4.2 Paint materials are often insoluble in common Karl Fischer solvents such as methanol. Pyridine has been found to be a nearly universal solvent for these materials; however, the Karl Fischer reaction is too slow in that solvent at room temperature. To speed it up, 1-ethylpiperidine is added at 5 % as a buffer, or “catalyst.” 4.3 For nonpyridine-based reagents, a number of different solvent systems are available to increase solubility and to minimize interferences from ketones and aldehydes.
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归口单位: D01.21
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