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现行 ASTM D5376-06(2021)
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Standard Test Method for Rubber Compounding Materials—Determination of the Basic Nitrogen Content in Rubber Antioxidant: Polymerized TMQ 橡胶复合材料的标准试验方法橡胶抗氧剂中碱性氮含量的测定:聚合TMQ
发布日期: 2021-11-01
1.1 本试验方法包括测定聚合2,2,4-三甲基-1,2-二氢喹啉(TMQ)的氮含量。它基于TMQ丙酮溶液与乙酸中高氯酸的电位滴定。 1.2 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.3 本标准并非旨在解决与其使用相关的所有安全问题(如有)。本标准的用户有责任在使用前制定适当的安全、健康和环境实践,并确定监管限制的适用性。 第节给出了具体的预防说明 9 . 1.4 本国际标准是根据世界贸易组织技术性贸易壁垒(TBT)委员会发布的《关于制定国际标准、指南和建议的原则的决定》中确立的国际公认标准化原则制定的。 ====意义和用途====== 5.1 本试验方法旨在测定低聚物2,2,4-三甲基-1,2-二氢喹啉(TMQ)抗氧化剂的氮含量。TMQ用于硫化橡胶的隔热。 5.2 本试验方法适用于评估产品规格,因为氮含量与产品性能有关,即抗氧化效率和耐热性。为了比较不同生产设施的产品质量,需要足够的实验室间精度和精密度。
1.1 This test method covers the determination of the nitrogen content of polymerized 2,2,4-trimethyl-1,2-dihydroquinoline (TMQ). It is based on a potentiometric titration of an acetone solution of TMQ with perchloric acid in acetic acid. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9 . 1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. ====== Significance And Use ====== 5.1 This test method is designed to determine the nitrogen content of oligomeric 2,2,4-trimethyl-1,2-dihydroquinoline (TMQ) antioxidant. TMQ is used for heat protection of vulcanized rubber. 5.2 This test method is suitable for assessing product specifications since nitrogen content is related to product performance, that is, antioxidant efficiency and heat protection. For comparison of product quality at different production facilities sufficient interlaboratory accuracy and precision are required.
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归口单位: D11.11
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