1.1 本试验方法涵盖地下水、地表水和饮用水中溶解元素的测定。它也可用于测定这些水和废水中的总可回收元素。 2. 1.2 本试验方法应由在电感耦合等离子体质谱（ICP-MS）的使用、光谱和基质干扰的解释及其校正程序方面有经验的分析员使用。 1.3 用户有责任确保未经测试基质水的测试方法的有效性。 1.4 表1 列出了试验方法适用的元素，以及使用传统气动雾化的推荐质量和典型估计仪器检测限。 实际工作检测限取决于样本，随着样本矩阵的变化，这些检测限也可能变化。随着更多信息的可用性和需要，可能会及时添加其他元素。 （A） 根据空白（1）的七次重复扫描估计仪器检测限（3σ） % v/v HNO 3. )和多元素标准的三次重复集成。 1.4.1 该方法包括分析2-120μg/L溶解锑和3-200μg/L溶解砷范围内的矿井排水地下水和废水。 1.4.2 该方法涵盖了1-500µg/L溶解金范围内冶金加工氰化物溶液的分析。 1.5 以国际单位制表示的数值应视为标准值。本标准不包括其他计量单位。 1.6 本标准并非旨在解决与其使用相关的所有安全问题（如有）。本标准的用户有责任在使用前制定适当的安全和健康实践，并确定监管限制的适用性。 ====意义和用途====== 5.1 该试验方法可用于测定许多天然水、冶金过程氰化物溶液和废水中的元素浓度。 它能够测定多达21种元素。对于其他技术难以确定的某些元素，可以实现高分析灵敏度。

1.1 This test method covers the determination of dissolved elements in ground water, surface water, and drinking water. It may also be used for the determination of total-recoverable elements in these waters as well as wastewater. 2 1.2 This test method should be used by analysts experienced in the use of inductively coupled plasma—mass spectrometry (ICP-MS), the interpretation of spectral and matrix interferences and procedures for their correction. 1.3 It is the user's responsibility to ensure the validity of the test method for waters of untested matrices. 1.4 Table 1 lists elements for which the test method applies, with recommended masses and typical estimated instrumental detection limits using conventional pneumatic nebulization. Actual working detection limits are sample dependent and, as the sample matrix varies, these detection limits may also vary. In time, other elements may be added as more information becomes available and as required. (A) Instrument detection limits (3σ) estimated from seven replicate scans of the blank (1 % v/v HNO 3 ) and three replicate integrations of a multi-element standard. 1.4.1 This method covers the analysis of mine dewatering groundwater and wastewater effluent in the range of 2–120 μg/L dissolved antimony and 3–200 μg/L dissolved arsenic. 1.4.2 This method covers the analysis of metallurgical processing cyanide solutions in the range of 1–500 µg/L dissolved gold. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. ====== Significance And Use ====== 5.1 The test method is useful for the determination of element concentrations in many natural waters, metallurgical process cyanide solutions and wastewaters. It has the capability for the determination of up to 21 elements. High analysis sensitivity can be achieved for some elements that are difficult to determine by other techniques.